Solvent induced single-crystal to single-crystal structural transformation and concomitant transmetalation in a 3D cationic Zn(II)-framework.
نویسندگان
چکیده
A 3D cationic Zn(II) framework, based on Zn2(CO2)4 paddle-wheel secondary building units (SBUs) and Zn16(CO2)32 polyhedral supramolecular building blocks (SBBs), has been synthesized. At room temperature, the framework undergoes guest solvent triggered reversible structural transformation and concomitant Zn(II) to Cu(II) transmetalation in a single-crystal to single-crystal fashion.
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 15 شماره
صفحات -
تاریخ انتشار 2015